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Dietary supplements are used by athletes worldwide. In the United States, the Dietary Supplement Health and Education Act has defined dietary supplements as something added to the diet, mainly (1) vitamins, (2) minerals, (3) amino acids, (4) herbs or botanicals, and (5) metabolites/constituents/extracts, or combination of any of these ingredients. In addition to actual food products targeted to athletes and physically-active individuals, numerous companies have marketed dietary supplements to athletes, often with the claim that sports performance may be enhanced. This is the first in a series of six articles to discuss the major classes of dietary supplements listed above. The major focus will be on efficacy of such dietary supplements to enhance exercise or sport performance, with brief coverage of safety, legality, and ethicality.Sports success is dependent primarily on genetic endowment in athletes with morphologic, psychologic, physiologic and metabolic traits specific to performance characteristics vital to their sport. Such genetically-endowed athletes must also receive optimal training to increase physical power, enhance mental strength, and provide a mechanical advantage. However, athletes often attempt to go beyond training and use substances and techniques, often referred to as ergogenics, in attempts to gain a competitive advantage. Pharmacological agents, such as anabolic steroids and amphetamines, have been used in the past, but such practices by athletes have led to the establishment of anti-doping legislation and effective testing protocols to help deter their use. Thus, many athletes have turned to various dietary strategies, including the use of various dietary supplements (sports supplements), which they presume to be effective, safe and legal.